﻿{"id":696,"date":"2012-08-27T23:21:04","date_gmt":"2012-08-27T19:21:04","guid":{"rendered":"http:\/\/nanobuild.ru\/en_EN\/?p=696"},"modified":"2014-08-27T23:22:24","modified_gmt":"2014-08-27T19:22:24","slug":"nanobuild-4-2014-pages-31-44","status":"publish","type":"post","link":"https:\/\/nanobuild.ru\/en_EN\/nanobuild-4-2014-pages-31-44\/","title":{"rendered":"Nanobuild-4-2014-pages-31-44"},"content":{"rendered":"<p style=\"text-align: justify;\"><strong>Pages:\u00a0\u00a0 31-44<\/strong><\/p>\n<p style=\"text-align: justify;\"><strong>\u00a0<\/strong><\/p>\n<p style=\"text-align: justify;\"><strong>Effect of surface treatment of carbon nanotubes on mechanical properties of cement composite<\/strong><\/p>\n<p style=\"text-align: justify;\"><strong>\u00a0<\/strong><\/p>\n<p style=\"text-align: justify;\"><strong>Authors:<\/strong>\u00a0 <strong>KONDAKOV Alexander Igorevich<\/strong>, Graduate student, Tambov State Technical University; Sovetskaya Str., 106, Tambov, Russia, 392000, bdiyoz@mail.ru;<\/p>\n<p style=\"text-align: justify;\"><strong>MIKHALEVA Zoya Alekseevna<\/strong>, Ph.D. in Engineering, Associate Professor of the Department<\/p>\n<p style=\"text-align: justify;\">\u00abTechnique and Technology of Nanoproducts Manufacture\u00bb, Tambov State Technical University; Sovetskaya Str., 106, Tambov, Russia, 392000, zoyamih3@gmail.com;<\/p>\n<p style=\"text-align: justify;\"><strong>TKACHEV Alexey Grigorievich<\/strong>, Doctor of Engineering, Professor, Head of the Department<\/p>\n<p style=\"text-align: justify;\">\u00abTechnique and Technology of Nanoproducts Manufacture\u00bb, Tambov State Technical University; Sovetskaya Str., 106, Tambov, Russia, 392000, postmaster@kma.tstu.ru;<\/p>\n<p style=\"text-align: justify;\"><strong>POPOV Andrey Ivanovich<\/strong>, Ph.D. in Pedagogics, Associate Professor of the Department \u00abTechnique and Technology of Nanoproducts Manufacture\u00bb, Tambov State Technical University; Sovetskaya Str., 106, Tambov, Russia, 392000, olimp_popov@mail.ru;<\/p>\n<p style=\"text-align: justify;\"><strong>GORSKI Sergey Yurevich<\/strong>, Master in Engineering and Technology, Graduate student, Tambov State Technical University; Sovetskaya Str., 106, Tambov, Russia, 392000, eshik_88@mail.ru<\/p>\n<p style=\"text-align: justify;\"><strong>\u00a0<\/strong><\/p>\n<p style=\"text-align: justify;\"><strong>Extended Abstract:<\/strong>The aim of the paper is to explore the influence of the carbon nanotubes functionalized by oxygen groups on the physical and mechanical properties of cement composites. Advantages and disadvantages of the main methods for the homogeneous distribution of carbon nanotubes (CNTs) in solution are discussed. A method for covalent functionalization of CNTs is described. An acid-base titration and dispersion analysis of solutions containing functionalized carbon nanotubes (f-CNTs) was performed. The research data made it possible to propose new technology of preparation of modified concrete.<\/p>\n<p style=\"text-align: justify;\">The results of the work can be used for designing of the additives commonly used in the construction industry, as well as for further studies of the effects of CNTs on the physical and mechanical and structural properties of building materials. Efficient modification of cement composite with f-CNTs was achieved at the concentration of f-CNTs ranging from 0.0004% to 0.0008% by weight of the binder. The observed increase of the concrete mechanical properties is explained by the fact that the CNTs act as nucleation centers for the cement hydration products.<\/p>\n<p style=\"text-align: justify;\">\n<p style=\"text-align: justify;\"><strong>Key words:<\/strong>\u00a0 carbon nanotubes, CNT, MCNT, cement composites, modification, functionalization of carbon nanotubes.<\/p>\n<p style=\"text-align: justify;\">\n<p style=\"text-align: justify;\"><strong><em>References:<\/em><\/strong><\/p>\n<p style=\"text-align: justify;\">1. <em>Rakov E.G. <\/em>Nanotrubki i fullereny: Uchebnoe posobie [Nanotubes and fullerenes: Textbook].<\/p>\n<p style=\"text-align: justify;\">Moscow, University Book, Logos, 2006, 376 p. (In Russian)<\/p>\n<p style=\"text-align: justify;\">2. <em>Konsta-Gdoutos S., Metaxa Z., Shah S. <\/em>Highly dispersed carbon nanotube reinforced cement<\/p>\n<p style=\"text-align: justify;\">based materials. Cement and Concrete Research. 2010, V. 40, pp. 1052\u20131059.<\/p>\n<p style=\"text-align: justify;\">3. <em>Li G., Wang P., Zhao X. <\/em>Mechanical behavior and microstructure of cement composites<\/p>\n<p style=\"text-align: justify;\">incorporating surface-treated multi-walled carbon nanotubes. Carbon. 2005, V. 43, pp.<\/p>\n<p style=\"text-align: justify;\">1239\u20131245.<\/p>\n<p style=\"text-align: justify;\">4. <em>Luo J., Duan Z., Li H. <\/em>The influence of surfactants on the processing of multi-walled carbon<\/p>\n<p style=\"text-align: justify;\">nanotubes in reinforced cement matrix composites. Phys. Status Solidi A. 2009, V. 206,<\/p>\n<p style=\"text-align: justify;\">\u2116 12, pp. 2783\u20132790.<\/p>\n<p style=\"text-align: justify;\">5. <em>Musso S.<\/em>, et al. Influence of carbon nanotubes structure on the mechanical behavior of cement composites. Composites Science and Technology. 2009, V. 69, pp. 1985\u20131990.<\/p>\n<p style=\"text-align: justify;\">6. <em>Nasibulina L.I.<\/em>, et al. Effect of carbon nanotube aqueous dispersion quality on mechanical<\/p>\n<p style=\"text-align: justify;\">properties of cement composite. Journal of Nanomaterials. 2012, V. 2012, \u2116 35, pp. 1\u20136.<\/p>\n<p style=\"text-align: justify;\">7. <em>Cwirzen A., Penttala V. <\/em>Surface decoration of carbon nanotubes and mechanical proper ties<\/p>\n<p style=\"text-align: justify;\">of cement\/carbon nanotube composites. Advances in Cement Research. 2008, V.20, \u2116 2,<\/p>\n<p style=\"text-align: justify;\">pp. 65\u201373.<\/p>\n<p style=\"text-align: justify;\">8. <em>Abu Al-Rub R.<\/em>, et al. Mechanical properties of nanocompositecement incorporating surfacetreated and untreated carbon nanotubes and carbon nanofibers. Journal of Nanomechanics and Micromechanics. 2012, V. 2, \u2116 1, pp. 1\u20136.<\/p>\n<p style=\"text-align: justify;\">9. <em>N. Aich, N. <\/em>et al. Applied TEM approach for micro \/nanostructural characterization of carbon<\/p>\n<p style=\"text-align: justify;\">nanotube reinforced cementitious composites. Journal of Research Updates in Polymer<\/p>\n<p style=\"text-align: justify;\">Science. 2012, \u2116 1, pp. 14\u201323.<\/p>\n<p style=\"text-align: justify;\">10. <em>Gorsky S.Y. <\/em>Issledovanie processov funkcionalizacii poverhnosti mnogoslojnyh uglerodnyh<\/p>\n<p style=\"text-align: justify;\">nanotrubok karboksil\u2019nymi gruppami [Investigation of the surface functionalization<\/p>\n<p style=\"text-align: justify;\">process of multiwalled carbon nanotubes by carboxyl groups] Master Thesis. TGTU, 2011,<\/p>\n<p style=\"text-align: justify;\">113 p. (In Russian)<\/p>\n<p style=\"text-align: justify;\">11. <em>Tolchkov Y.N., Mikhaleva Z.A. <\/em>Development of nanomodifiers based CNM \u00abTaunit\u00bb in<\/p>\n<p style=\"text-align: justify;\">building composites. I mezhdunarodnaja klasternaja nauchno-prakticheskaja konferencija<\/p>\n<p style=\"text-align: justify;\">\u00abAspekty noosfernoj bezo-pasnosti v prioritetnyh napravlenijah dejatel\u2019nosti cheloveka\u00bb<\/p>\n<p style=\"text-align: justify;\">[Proc. of the II International Cluster scientific-practical conference \u00abAspects noosphere<\/p>\n<p style=\"text-align: justify;\">security in priority areas of human activity\u00bb]. Tambov, 2011, pp. 121\u2013125. (In Russian)<\/p>\n<p style=\"text-align: justify;\">12. Development of technology for nanostructured additives for high-strength concrete (report)<\/p>\n<p style=\"text-align: justify;\">541.16:536.4, Inv. Number 001, OOO \u00abNanostroyteh\u00bb Gabidullin M.G. Kazan, 2012. 55 p.<\/p>\n<p style=\"text-align: justify;\">13. <em>Tkachev A.G, Mikhaleva Z.A., Popov A.I., Tolchkov Y.N., Panina T.I. <\/em>Investigation of the<\/p>\n<p style=\"text-align: justify;\">effect modifiers based gel dispersion properties of carbon nanomaterials in building composites. Nanotehnologii v stroitel\u2019stve = Nanotechnologies in Construction. 2012, Vol. 4,<\/p>\n<p style=\"text-align: justify;\">no 1, pp. 15\u201323. Available at: http:\/\/nanobuild.ru\/en_EN\/ (Accessed 10.08.2014)<\/p>\n<p style=\"text-align: justify;\"><strong>\u00a0<\/strong><\/p>\n<p style=\"text-align: justify;\"><a title=\"Nanobuild-4-2014-pages-31-44\" href=\"\/en_EN\/journal\/Nanobuild-4-2014\/31-44.pdf\"><strong>Full text in PDF format (31-44)<\/strong><\/a><\/p>\n<p style=\"text-align: justify;\"><strong>\u00a0<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Pages:\u00a0\u00a0 31-44 \u00a0 Effect of surface treatment of carbon nanotubes on mechanical properties of cement composite \u00a0 Authors:\u00a0 KONDAKOV Alexander Igorevich, Graduate student, Tambov State Technical University; Sovetskaya Str., 106, Tambov, Russia, 392000, bdiyoz@mail.ru; MIKHALEVA Zoya Alekseevna, Ph.D. in Engineering, <span class=\"readmore\"><a class=\"more-link\" href=\"https:\/\/nanobuild.ru\/en_EN\/nanobuild-4-2014-pages-31-44\/\">Read More &#8230;<\/a><\/span><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"class_list":["post-696","post","type-post","status-publish","format-standard","hentry","category-1"],"_links":{"self":[{"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/posts\/696","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/comments?post=696"}],"version-history":[{"count":1,"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/posts\/696\/revisions"}],"predecessor-version":[{"id":697,"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/posts\/696\/revisions\/697"}],"wp:attachment":[{"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/media?parent=696"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/categories?post=696"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/nanobuild.ru\/en_EN\/wp-json\/wp\/v2\/tags?post=696"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}